The effects of metal surface geometry on the formation of uranium hydride
File(s)
Author(s)
Stitt, CA
Paraskevoulakos, C
Harker, NJ
Jones, CP
Scott, TB
Type
Journal Article
Abstract
The present work examines the effect of surface geometry on the reaction between hydrogen gas and uranium metal, forming uranium hydride (UH3), a pyrophoric compound of significance to the civil nuclear industry. Hydride formation was initiated on uranium samples that had been patterned with a focused ion beam instrument to form surface arrays of triangular prisms and pillars with differing apex angles. Post reaction analysis indicated preferential hydride formation at the apex of these features. Additionally, once hydride formation had commenced the observed growth rate on the prisms appeared to accelerate in comparison to the rate exhibited on the surrounding surface.
Date Issued
2015-05-27
Date Acceptance
2015-05-10
Citation
Corrosion Science, 2015, 98, pp.63-71
ISSN
0010-938X
Publisher
Elsevier
Start Page
63
End Page
71
Journal / Book Title
Corrosion Science
Volume
98
Copyright Statement
© 2015, Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Subjects
0912 Materials Engineering
0905 Civil Engineering
0913 Mechanical Engineering
Energy
Notes
publisher: Elsevier articletitle: The effects of metal surface geometry on the formation of uranium hydride journaltitle: Corrosion Science articlelink: http://dx.doi.org/10.1016/j.corsci.2015.05.010 content_type: article copyright: Copyright © 2015 Elsevier Ltd. All rights reserved.
Publication Status
Published