How solar cell efficiency is governed by the αμτ product
File(s)PhysRevResearch.2.023109.pdf (2.21 MB)
Published version
Author(s)
Type
Journal Article
Abstract
The interplay of light absorption, charge-carrier transport, and charge-carrier recombination determines the performance of a photovoltaic absorber material. Here we analyze the influence on the solar-cell efficiency of the absorber material properties absorption coefficient α, charge-carrier mobility μ, and charge-carrier lifetime τ, for different scenarios. We combine analytical calculations with numerical drift-diffusion simulations to understand the relative importance of these three quantities. Whenever charge collection is a limiting factor, the αμτ product is a good figure of merit (FOM) to predict solar-cell efficiency, while for sufficiently high mobilities, the relevant FOM is reduced to the ατ product. We find no fundamental difference between simulations based on monomolecular or bimolecular recombination, but strong surface-recombination affects the maximum efficiency in the high-mobility limit. In the limiting case of high
μ
and high surface-recombination velocity
S
, the
α
/
S
ratio is the relevant FOM. Subsequently, we apply our findings to organic solar cells which tend to suffer from inefficient charge-carrier collection and whose absorptivity is influenced by interference effects. We estimate that a modest increase in absorption strength by a factor of 1.5 leads to a relative efficiency increase of more than 10% for state-of-the-art organic solar cells.
μ
and high surface-recombination velocity
S
, the
α
/
S
ratio is the relevant FOM. Subsequently, we apply our findings to organic solar cells which tend to suffer from inefficient charge-carrier collection and whose absorptivity is influenced by interference effects. We estimate that a modest increase in absorption strength by a factor of 1.5 leads to a relative efficiency increase of more than 10% for state-of-the-art organic solar cells.
Date Issued
2020-04-30
Date Acceptance
2020-03-15
Citation
Physical Review Research, 2020, 2 (2), pp.023109 – 1-023109 – 15
ISSN
2643-1564
Publisher
American Physical Society
Start Page
023109 – 1
End Page
023109 – 15
Journal / Book Title
Physical Review Research
Volume
2
Issue
2
Copyright Statement
© 2020 The Author(s). Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.
License URL
Sponsor
Commission of the European Communities
Identifier
https://journals.aps.org/prresearch/abstract/10.1103/PhysRevResearch.2.023109
Grant Number
742708
Publication Status
Published
Article Number
023109
Date Publish Online
2020-04-30