Dynamics of the first-order metamagnetic transition in magnetocaloric La(Fe,Si)(13): Reducing hysteresis
File(s)AdvEnergyMaterELovell ReSubmit FINAL.doc (599 KB)
Accepted version
Author(s)
Lovell, E
Pereira, AM
Caplin, AD
Lyubina, J
Cohen, LF
Type
Journal Article
Abstract
The influence of dynamics and sample shape on the magnetic hysteresis in first‐order magnetocaloric metamagnetic LaFe13–xSix with x = 1.4 is studied. In solid‐state magnetic cooling, reducing magnetic and thermal hysteresis is critical for refrigeration cycle efficiency. From magnetization measurements, it is found that the fast field‐rate dependence of the hysteresis can be attributed to extrinsic heating directly related to the thickness of the sample and the thermal contact with the bath. If the field is paused partway through the transition, the subsequent relaxation is strongly dependent on shape due to both demagnetizing fields and thermal equilibration; magnetic coupling between adjacent sample fragments can also be significant. Judicious shaping of the sample can both increase the onset field of the ferromagnetic–paramagnetic (FM–PM) transition but have little effect on the PM–FM onset, suggesting a route to engineer the hysteresis width by appropriate design. In the field‐paused state, the relaxation from one phase to the other slows with increasing temperature, implying that the process is neither thermally activated or athermal; comparison with the temperature dependence of the latent heat strongly suggests that the dynamics reflect the intrinsic free energy difference between the two phases.
Date Issued
2015-03-18
Date Acceptance
2014-11-01
Citation
Advanced Energy Materials, 2015, 5 (6)
ISSN
1614-6840
Publisher
Wiley-VCH Verlag
Journal / Book Title
Advanced Energy Materials
Volume
5
Issue
6
Copyright Statement
This is the peer reviewed version of the following article: Lovell E., Pereira A. M., Caplin A. D., Lyubina J., Cohen L. F. (2015). Dynamics of the First-Order Metamagnetic Transition in Magnetocaloric La(Fe,Si)13: Reducing Hysteresis. Adv. Energy Mater., 5: . doi: 10.1002/aenm.201401639, which has been published in final form at [http://onlinelibrary.wiley.com/doi/10.1002/aenm.201401639/abstract]. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://onlinelibrary.wiley.com/doi/abs/10.1002/aenm.201401639
Grant Number
EP/E016243/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Energy & Fuels
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Chemistry
Materials Science
Physics
hysteresis
magnetic refrigeration
magnetic relaxation
magnetocaloric effects
metamagnetism
MAGNETIC REFRIGERATION
PHASE-TRANSITIONS
PERFORMANCE
Publication Status
Published
Article Number
1401639
Date Publish Online
2014-11-29