A morphological study of ceramic hollow fibre membranes
File(s)Journal of Membrane Science_328_1-2_2009.pdf (447.71 KB)
Accepted version
Author(s)
Kingsbury, Benjamin FK
Li, K
Type
Journal Article
Abstract
Morphologies of ceramic hollow fibre membranes prepared from suspensions of Al(2)O(3), NMP (N-methyl-2-pyrrolidone) and polyethersulfone (PESf) using a dry-wet spinning/sintering process have been studied experimentally The results indicate that two types of membrane morphologies, i.e. finger-like and sponge-like structures can be expected. It is believed that finger-like void formation in asymmetric ceramic membranes is initiated by hydrodynamically unstable viscous fingering developed when a less viscous fluid (non-solvent) is in contact with a higher viscosity fluid (ceramic suspension containing invertible polymer binder). Finger-like void growth occurs only below a critical suspension viscosity, above which a sponge-like structure is observed over the entire hollow fibre cross-section. The effects of the air-gap, viscosity and non-solvent concentration on fibre morphology have been studied and it has been determined that viscosity is the dominating factor for ceramic systems. Crown (c) 2008 Published by Elsevier B.V. All rights reserved.
Date Issued
2009-02-20
Citation
JOURNAL OF MEMBRANE SCIENCE, 2009, 328 (1-2), pp.134-140
ISSN
0376-7388
Publisher
ELSEVIER SCIENCE BV
Start Page
134
End Page
140
Journal / Book Title
JOURNAL OF MEMBRANE SCIENCE
Volume
328
Issue
1-2
Copyright Statement
Crown copyright © 2008 Published by Elsevier B.V. All rights reserved. NOTICE: this is the author’s version of a work that was accepted for publication in Journal of Membrane Science. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Journal of Membrane Science, 328(1-2), 2009. DOI:10.1016/j.memsci.2008.11.050
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=000263891600017&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Physical Sciences
Engineering, Chemical
Polymer Science
Engineering
Alumina
Asymmetric membrane
Hollow fibres
Morphology
PHASE-INVERSION
ASYMMETRIC MEMBRANES
REACTOR
PRECIPITATION
Publication Status
Published