Trisiloxane-centred metal-organic frameworks and hydrogen bonded assemblies
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Author(s)
Type
Journal Article
Abstract
A hexacarboxylic acid with a trisiloxane backbone (L-H6) has been prepared and applied in MOF construction. L-H6 itself crystallizes as an unusual 2D hydrogen-bonded network. Reaction of L-H6 with Mn(II) gave IMP-20 and with Zn(II) gave IMP-21: both are 3D MOFs incorporating Si–O–Si–O–Si linkages.
Date Issued
2018-08-28
Date Acceptance
2018-06-25
Citation
CrystEngComm, 2018, 20, pp.4541-4545
ISSN
1466-8033
Publisher
Royal Society of Chemistry
Start Page
4541
End Page
4545
Journal / Book Title
CrystEngComm
Volume
20
Copyright Statement
© The Royal Society of Chemistry 2018. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/)
Subjects
0306 Physical Chemistry (Incl. Structural)
0912 Materials Engineering
0302 Inorganic Chemistry
Inorganic & Nuclear Chemistry
Publication Status
Published
Date Publish Online
2018-08-02