Effect of pressure on the flow behavior of polybutene
File(s)
Author(s)
Ponjavic, A
di Mare, L
Wong, J
Type
Journal Article
Abstract
The rheology of submicron thick polymer melt is examined under high normal pressure conditions by a recently developed photobleached‐fluorescence imaging velocimetry technique. In particular, the validity and limitation of Reynold equation solution, which suggests a linear through‐thickness velocity profile, is investigated. Polybutene (PB) is sheared between two surfaces in a point contact. The results presented in this work suggest the existence of a critical pressure below which the through‐thickness velocity profile is close to linear. At higher pressures however, the profile assumes a sigmoidal shape resembling partial plug flow. The departure of the sigmoidal profile from the linear profile increases with pressure, which is indicative of a second‐order phase/glass transition. The nature of the transition is confirmed independently by examining the pressure‐dependent dynamics of PB squeeze films. The critical pressure for flow profile transition varies with molecular weight, which is consistent with the pressure‐induced glass transition of polymer melt.
Date Issued
2014-03-15
Date Acceptance
2014-03-04
Citation
Journal of Polymer Science Part B: Polymer Physics, 2014, 52 (10), pp.708-715
ISSN
0887-6266
Publisher
Wiley
Start Page
708
End Page
715
Journal / Book Title
Journal of Polymer Science Part B: Polymer Physics
Volume
52
Issue
10
Copyright Statement
© 2014 Wiley Periodicals, Inc.This is the peer reviewed version of the following article: Ponjavic, A., di Mare, L. and Wong, J. S. S. (2014), Effect of pressure on the flow behavior of polybutene. J. Polym. Sci. B Polym. Phys., 52: 708–715. doi: 10.1002/polb.23472, which has been published in final form at [Link to final article using the DOI]. This article may be used for non-commercial purposes in accordance With Wiley Terms and Conditions for self-archiving.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://onlinelibrary.wiley.com/doi/abs/10.1002/polb.23472
Grant Number
EP/J015385/1
EP/G026114/1
Subjects
Science & Technology
Physical Sciences
Polymer Science
glass transition
rheology
shear
viscosity
GLASS-TRANSITION TEMPERATURE
CONFINED POLYMER MELTS
LIQUID LUBRICANTS
SHEAR
RHEOLOGY
FLUORESCENCE
SURFACE
FILMS
VISCOSITY
DYNAMICS
Polymers
02 Physical Sciences
03 Chemical Sciences
09 Engineering
Publication Status
Published
Date Publish Online
2014-03-18