Underscreening, overscreening and double-layer capacitance
File(s)NMD_EC_8.pdf (549.23 KB)
Accepted version
Author(s)
Goodwin, ZAH
Kornyshev, AA
Type
Journal Article
Abstract
There have recently been reports of extraordinarily long screening lengths in concentrated electrolytes and which vary non-monotonically with ion concentration. There were several attempts to explain these puzzling observations. In this communication we further explore possibilities to rationalise those results. Our analysis does not yet close the problem, but it highlights conflicting consequences of the models designed to reproduce those observations.
Date Issued
2017-07-13
Date Acceptance
2017-07-11
Citation
ELECTROCHEMISTRY COMMUNICATIONS, 2017, 82, pp.129-133
ISSN
1388-2481
Publisher
ELSEVIER SCIENCE INC
Start Page
129
End Page
133
Journal / Book Title
ELECTROCHEMISTRY COMMUNICATIONS
Volume
82
Copyright Statement
© 2017 Published by Elsevier B.V. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000408359600029&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Electrochemistry
Concentrated electrolytes
Room temperature ionic liquids
Debye length
Mean-field
Underscreening
Overscreening
TEMPERATURE IONIC LIQUIDS
ELECTRICAL DOUBLE-LAYER
DIFFERENTIAL CAPACITANCE
INTERFACES
MODEL
ELECTROLYTES
ELECTRODES
DYNAMICS
SURFACES
AU(111)
03 Chemical Sciences
09 Engineering
Energy
Publication Status
Published