Limits to crystallization pressure
File(s)Limits to Crystallization Pressure.pdf (4.94 MB)
Published version
Author(s)
Type
Journal Article
Abstract
Crystallization pressure drives deformation and damage in monuments, buildings, and the Earth’s crust. Even though the phenomenon has been known for 170 years, there is no agreement between theoretical calculations of the maximum attainable pressure and experimentally measured pressures. We have therefore developed a novel experimental technique to image the nanoconfined crystallization process while controlling the pressure and applied it to calcite. The results show that displacement by crystallization pressure is arrested at pressures well below the thermodynamic limit. We use existing molecular dynamics simulations and atomic force microscopy data to construct a robust model of the disjoining pressure in this system and thereby calculate the absolute distance between the surfaces. On the basis of the high-resolution experiments and modeling, we formulate a novel mechanism for the transition between damage and adhesion by crystallization that may find application in Earth and materials sciences and in conservation of cultural heritage.
Date Issued
2022-09-09
Date Acceptance
2022-09-01
Citation
Langmuir: the ACS journal of surfaces and colloids, 2022, 38 (37), pp.11265-11273
ISSN
0743-7463
Publisher
American Chemical Society
Start Page
11265
End Page
11273
Journal / Book Title
Langmuir: the ACS journal of surfaces and colloids
Volume
38
Issue
37
Copyright Statement
Copyright © 2022 The Authors. Published by American Chemical Society. This work is published under a CC BY licence.
License URL
Identifier
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000854357500001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
Subjects
CALCITE SURFACES
Chemistry
Chemistry, Multidisciplinary
Chemistry, Physical
CRYSTAL
DAMAGE
FORCES
GROWTH
HYDRATION
Materials Science
Materials Science, Multidisciplinary
Physical Sciences
Science & Technology
STRENGTH
Technology
Publication Status
Published
Date Publish Online
2022-09-09