ZnO nanorod arrays as electron injection layers for efficient organic light emitting diodes
File(s)Spiral accepted version.pdf (2.55 MB)
Accepted version
Author(s)
Faria, JCD
Campbell, AJ
McLachlan, MA
Type
Journal Article
Abstract
Nanostructured oxide arrays have received significant attention as charge injection and collection electrodes in numerous optoelectronic devices. Zinc oxide (ZnO) nanorods have received particular interest owing to the ease of fabrication using scalable, solution processes with a high degree of control of rod dimension and density. Here, vertical ZnO nanorods as electron injection layers in organic light emitting diodes are implemented for display and lighting purposes. Implementing nanorods into devices with an emissive polymer, poly(9,9-dioctyluorene-alt-benzothiadiazole) (F8BT) and poly(9,9-di-n-octylfluorene-alt-N-(4-butylphenyl)dipheny-lamine) (TFB) as an electron blocking layer, brightness and efficiencies up to 8602 cd m−2 and 1.66 cd A−1 are achieved. Simple solution processing methodologies combined with postdeposition thermal processing are highlighted to achieve complete wetting of the nanorod arrays with the emissive polymer. The introduction of TFB to minimize charge leakage and nonradiative exciton decay results in dramatic increases to device yields and provides an insight into the operating mechanism of these devices. It is demonstrated that the detected emission originates from within the polymer layers with no evidence of ZnO band edge or defect emission. The work represents a significant development for the ongoing implementation of ZnO nanorod arrays into efficient light emitting devices.
Date Issued
2015-06-18
Date Acceptance
2015-05-05
Citation
Advanced Functional Materials, 2015, 25 (29), pp.4657-4663
ISSN
1616-3028
Publisher
Wiley
Start Page
4657
End Page
4663
Journal / Book Title
Advanced Functional Materials
Volume
25
Issue
29
Copyright Statement
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article, 'ZnO Nanorod Arrays as Electron Injection Layers for Efficient Organic Light Emitting Diodes', which has been published in final form at: http://dx.doi.org/10.1002/adfm.201501411.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Kaust
Engineering and Physical Sciences Research Council
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000359025700011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
EP/F056362/1
EP/J016039/1
N/A
EP/G037515/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Multidisciplinary
Chemistry, Physical
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Physics, Applied
Physics, Condensed Matter
Chemistry
Science & Technology - Other Topics
Materials Science
Physics
conjugated polymers
nanorods
organic electronics
light-emitting diodes
zinc oxide
HYDROTHERMAL GROWTH
PHOTOVOLTAIC DEVICES
PPV HETEROSTRUCTURE
OPTICAL-PROPERTIES
SOLAR-CELLS
ELECTROLUMINESCENCE
MORPHOLOGY
NANOSTRUCTURES
COPOLYMER
ALIGNMENT
Materials
03 Chemical Sciences
09 Engineering
02 Physical Sciences
Publication Status
Published