Unveiling and manipulating hidden symmetries in graphene nanoribbons
File(s)
Author(s)
Tepliakov, Nikita V
Lischner, Johannes
Kaxiras, Efthimios
Mostofi, Arash A
Pizzochero, Michele
Type
Journal Article
Abstract
Armchair graphene nanoribbons are a highly promising class of semiconductors for all-carbon nanocircuitry. Here, we present a new perspective on their electronic structure from simple model Hamiltonians and ab initio calculations. We focus on a specific set of nanoribbons of width
n
=
3
p
+
2
, where
n
is the number of carbon atoms across the nanoribbon axis and
p
is a positive integer. We demonstrate that the energy-gap opening in these nanoribbons originates from the breaking of a previously unidentified hidden symmetry by long-ranged hopping of
π
electrons and structural distortions occurring at the edges. This hidden symmetry can be restored or manipulated through the application of in-plane lattice strain, which enables continuous energy-gap tuning, the emergence of Dirac points at the Fermi level, and topological quantum phase transitions. Our work establishes an original interpretation of the semiconducting character of armchair graphene nanoribbons and offers guidelines for rationally designing their electronic structure.
n
=
3
p
+
2
, where
n
is the number of carbon atoms across the nanoribbon axis and
p
is a positive integer. We demonstrate that the energy-gap opening in these nanoribbons originates from the breaking of a previously unidentified hidden symmetry by long-ranged hopping of
π
electrons and structural distortions occurring at the edges. This hidden symmetry can be restored or manipulated through the application of in-plane lattice strain, which enables continuous energy-gap tuning, the emergence of Dirac points at the Fermi level, and topological quantum phase transitions. Our work establishes an original interpretation of the semiconducting character of armchair graphene nanoribbons and offers guidelines for rationally designing their electronic structure.
Date Issued
2023-01-13
Date Acceptance
2022-12-23
Citation
Physical Review Letters, 2023, 130 (2), pp.1-6
ISSN
0031-9007
Publisher
American Physical Society
Start Page
1
End Page
6
Journal / Book Title
Physical Review Letters
Volume
130
Issue
2
Copyright Statement
© 2023 American Physical Society
Identifier
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000919680000011&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
BAND-GAP
Physical Sciences
Physics
Physics, Multidisciplinary
Science & Technology
Publication Status
Published
Article Number
026401
Date Publish Online
2023-01-12