An in situ and ex situ TEM study into the oxidation of titanium (IV) sulphide
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Published version
Author(s)
Type
Journal Article
Abstract
Titanium (IV) sulphide (TiS2) is a layered transition metal dichalcogenide, which we exfoliate using liquid phase exfoliation. TiS2 is a candidate for being part of a range of future technologies. These applications are varied, and include supercapacitor and battery energy storage devices, catalytic substrates and the splitting of water. The driving force behind our interest was as a material for energy storage devices. Here we investigate a potential failure mechanism for such devices, namely oxidation and subsequent loss of sulphur. This degradation is important to understand, since these applications are highly property-dependent, and changes to the chemistry will result in changes in desired properties. Two approaches to study oxidisation were taken: ex situ oxidation by water and oxygen at room temperature and in situ oxidation by a 5% O2/Ar gas at elevated temperatures. Both sources of oxygen resulted in oxidation of the starting TiS2 flakes, with differing morphologies. Water produced amorphous oxide slowly growing in from the edge of the flakes. Oxygen gas at ≥375 °C produced crystalline oxide, with a range of structures due to oxidation initiating from various regions of the observed flakes.
Date Issued
2017-12-01
Date Acceptance
2017-06-16
Citation
npj 2D Materials and Applications, 2017, 1 (1)
ISSN
2397-7132
Publisher
Nature Research (part of Springer Nature)
Journal / Book Title
npj 2D Materials and Applications
Volume
1
Issue
1
Copyright Statement
© 2017 The Author(s). This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
Publication Status
Published
Article Number
22
Date Publish Online
2017-07-10