Hydrogen in Ti and Zr alloys: industrial perspective, failure modes and mechanistic understanding
File(s)PTA-Ti_Zr_H_Effects_Final-c.pdf (11.98 MB)
Accepted version
Author(s)
Chapman, TP
Dye, D
Rugg, D
Type
Journal Article
Abstract
Titanium is widely used in demanding applications, such as in aerospace. Its strength-to-weight ratio and
corrosion resistance make it well suited to highly stressed rotating components. Zirconium has a no less
critical application where its low neutron capture cross section and good corrosion resistance in hot water and
steam make it well suited to reactor core use, including fuel cladding and structures. The similar metallurgical
behaviour of these alloy systems make it alluring to compare and contrast their behaviour. This is rarely
undertaken, mostly because the industrial and academic communities studying these alloys have little
overlap. The similarities with respect to hydrogen are remarkable, albeit potentially unsurprising, and so this
paper aims to provide an overview of the role hydrogen has to play through the material life cycle. This
includes the relationship between alloy design and manufacturing process windows, the role of hydrogen in
degradation and failure mechanisms and some of the underpinning metallurgy. The potential role of
some advanced experimental and modelling techniques will also be explored to give a tentative view of
potential for advances in this field in the next decade or so.
corrosion resistance make it well suited to highly stressed rotating components. Zirconium has a no less
critical application where its low neutron capture cross section and good corrosion resistance in hot water and
steam make it well suited to reactor core use, including fuel cladding and structures. The similar metallurgical
behaviour of these alloy systems make it alluring to compare and contrast their behaviour. This is rarely
undertaken, mostly because the industrial and academic communities studying these alloys have little
overlap. The similarities with respect to hydrogen are remarkable, albeit potentially unsurprising, and so this
paper aims to provide an overview of the role hydrogen has to play through the material life cycle. This
includes the relationship between alloy design and manufacturing process windows, the role of hydrogen in
degradation and failure mechanisms and some of the underpinning metallurgy. The potential role of
some advanced experimental and modelling techniques will also be explored to give a tentative view of
potential for advances in this field in the next decade or so.
Date Issued
2017-06-12
Date Acceptance
2017-03-09
Citation
Philosophical transactions. Physical sciences and engineering, 2017, 375
ISSN
0962-8428
Publisher
The Royal Society
Journal / Book Title
Philosophical transactions. Physical sciences and engineering
Volume
375
Copyright Statement
© 2017 The Author(s) Published by the Royal Society. All rights reserved.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Grant Number
EP/K034332/1
138874
Subjects
Science & Technology
Multidisciplinary Sciences
Science & Technology - Other Topics
titanium
zirconium
SIMS
STEM
stress corrosion
hydrogen
DELAYED HYDRIDE CRACKING
BETA-TITANIUM-ALLOYS
SUSTAINED-LOAD CRACKING
ZIRCONIUM ALLOYS
ALPHA-TITANIUM
ASSISTED CRACKING
EMBRITTLEMENT
FATIGUE
MICROSTRUCTURE
SOLUBILITY
MD Multidisciplinary
General Science & Technology
Publication Status
Published
Article Number
20160418