A geochemical study of the winonaites: Evidence for limited partial melting and constraints on the precursor composition
File(s)Hunt et al for MR.PDF (1.29 MB)
Accepted version
Author(s)
Type
Journal Article
Abstract
The winonaites are primitive achondrites which are associated with the IAB iron meteorites. Textural evidence implies heating to at least the Fe, Ni-FeS cotectic, but previous geochemical studies are ambiguous about the extent of silicate melting in these samples. Oxygen isotope evidence indicates that the precursor material may be related to the carbonaceous chondrites. Here we analysed a suite of winonaites for modal mineralogy and bulk major- and trace-element chemistry in order to assess the extent of thermal processing as well as constrain the precursor composition of the winonaite
-IAB parent asteroid. Modal mineralogy and geochemical data are presented for eight winonaites. Textural analysis reveals that, for our sub-set of samples, all except the most primitive winonaite
(Northwest Africa 1463) reached the Fe, Ni-FeS cotectic. However, only one (Tierra Blanca)
shows geochemical evidence for silicate melting processes. Tierra Blanca is interpreted as a
residue of small-degree silicate melting. Our sample of Winona shows geochemical evidence
for extensive terrestrial weathering. All other winonaites studied here (Fortuna, Queen Alexander Range 94535, Hammadah al Hamra 193, Pontlyfni and NWA 1463) have chondritic major-element ratios and flat CI-normalised bulk rare-earth element patterns, suggesting that most of the winonaites did not reach the silicate melting temperature. The majority of winonaites were therefore heated to a narrow temperature range of between ~1220 (the Fe, Ni-FeS cotectic temperature) and ~1370 K (the basaltic partial melting temperature). Silicate inclusions in the IAB irons demonstrate partial melting did occur in some parts of the parent body (Ruzicka and Hutson, 2010), thereby implying heterogeneous heat distribution within this asteroid. Together, this indicates that melting was the result of internal heating by short-lived radionuclides. The brecciated nature of the winonaites suggests that the parent body was later disrupted by a catastrophic impact, which allowed the preservation of the largely unmelted winonaites. Despite major-element similarities to both ordinary and enstatite chondrites, trace-element analysis suggests the winonaite parent body had a arbonaceous chondrite-like precursor composition. The parent body of the winonaites was volatile -depleted relative to CI, but enriched compared to the other carbonaceous classes. The closest match are the CM
chondrites, however, the specific precursor is not sampled in current meteorite collections.
-IAB parent asteroid. Modal mineralogy and geochemical data are presented for eight winonaites. Textural analysis reveals that, for our sub-set of samples, all except the most primitive winonaite
(Northwest Africa 1463) reached the Fe, Ni-FeS cotectic. However, only one (Tierra Blanca)
shows geochemical evidence for silicate melting processes. Tierra Blanca is interpreted as a
residue of small-degree silicate melting. Our sample of Winona shows geochemical evidence
for extensive terrestrial weathering. All other winonaites studied here (Fortuna, Queen Alexander Range 94535, Hammadah al Hamra 193, Pontlyfni and NWA 1463) have chondritic major-element ratios and flat CI-normalised bulk rare-earth element patterns, suggesting that most of the winonaites did not reach the silicate melting temperature. The majority of winonaites were therefore heated to a narrow temperature range of between ~1220 (the Fe, Ni-FeS cotectic temperature) and ~1370 K (the basaltic partial melting temperature). Silicate inclusions in the IAB irons demonstrate partial melting did occur in some parts of the parent body (Ruzicka and Hutson, 2010), thereby implying heterogeneous heat distribution within this asteroid. Together, this indicates that melting was the result of internal heating by short-lived radionuclides. The brecciated nature of the winonaites suggests that the parent body was later disrupted by a catastrophic impact, which allowed the preservation of the largely unmelted winonaites. Despite major-element similarities to both ordinary and enstatite chondrites, trace-element analysis suggests the winonaite parent body had a arbonaceous chondrite-like precursor composition. The parent body of the winonaites was volatile -depleted relative to CI, but enriched compared to the other carbonaceous classes. The closest match are the CM
chondrites, however, the specific precursor is not sampled in current meteorite collections.
Date Issued
2016-11-02
Date Acceptance
2016-10-27
Citation
Geochimica et Cosmochimica Acta, 2016, 199, pp.13-30
ISSN
0016-7037
Start Page
13
End Page
30
Journal / Book Title
Geochimica et Cosmochimica Acta
Volume
199
Copyright Statement
© 2016 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Science and Technology Facilities Council (STFC)
Grant Number
ST/J001260/1
Subjects
Science & Technology
Physical Sciences
Geochemistry & Geophysics
Winonaite
Primitive achondrite
IAB iron meteorite
Precursor material
Metal-silicate separation
ICP-MS
LODRANITE PARENT BODY
IAB IRON-METEORITES
SILICATE INCLUSIONS
OXYGEN-ISOTOPE
FORSTERITE CHONDRITES
CHEMICAL-ANALYSES
STONY METEORITES
SOLAR-SYSTEM
EVOLUTION
ACHONDRITES
0402 Geochemistry
0403 Geology
Publication Status
Published