Anthropogenic emissions of volatile Cd detected in western tropical North Atlantic surface seawater
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Author(s)
Type
Journal Article
Abstract
The Cd concentrations and isotope compositions of open ocean surface waters are generally thought to be governed by internal cycling, and particularly by the balance between upwelling of more Cd-rich deeper water masses and Cd uptake by phytoplankton. Here we present a new dataset of coupled Cd isotope compositions and concentrations for seawater depth profiles
sampled in the western tropical Atlantic Ocean during Leg 2 of the GEOTRACES GA02 section. A box model for the Cd source and sink fluxes of the oligotrophic surface waters of the study area shows that the observed light Cd isotope compositions and low Cd concentrations are a consequence of biological Cd uptake and atmospheric deposition of isotopically light anthropogenic Cd. Aerosols enriched in anthropogenic Cd thereby contributed at least 19%, and possibly more than 45%, to the dissolved surface water Cd inventory during the sampling period. This reveals that anthropogenic emissions of volatile Cd
can have a key impact on the distribution of Cd in open ocean surface waters.
sampled in the western tropical Atlantic Ocean during Leg 2 of the GEOTRACES GA02 section. A box model for the Cd source and sink fluxes of the oligotrophic surface waters of the study area shows that the observed light Cd isotope compositions and low Cd concentrations are a consequence of biological Cd uptake and atmospheric deposition of isotopically light anthropogenic Cd. Aerosols enriched in anthropogenic Cd thereby contributed at least 19%, and possibly more than 45%, to the dissolved surface water Cd inventory during the sampling period. This reveals that anthropogenic emissions of volatile Cd
can have a key impact on the distribution of Cd in open ocean surface waters.
Date Issued
2026-02-19
Date Acceptance
2026-01-09
Citation
Communications Earth & Environment, 2026, 7
ISSN
2662-4435
Publisher
Nature Portfolio
Journal / Book Title
Communications Earth & Environment
Volume
7
Copyright Statement
©The Author(s) 2026 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
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Publication Status
Published
Article Number
181
Date Publish Online
2026-01-22