We report the electronic structure of two metal-organic frameworks (MOFs) with copper paddle wheel nodes connected by a N₂(C₂H₄)₃ (DABCO) ligand with accessible nitrogen lone pairs. The coordination is predicted, from first-principles density functional theory, to enable electronic pathways that could facilitate charge carrier mobility. Calculated frontier crystal orbitals indicate extended electronic communication in DMOF-1, but not in MOF-649. This feature is confirmed by bandstructure calculations and effective masses of the valence band egde. We explain the origin of the frontier orbitals of both MOFs based on the energy and symmetry alignment of the underlying building blocks. The effects of doping on the bandstructure of MOF-649 are considered. Our findings highlight DMOF-1 as a potential semiconductor with 1D charge carrier mobility along the framework