Corrosion rates under charge-conservation conditions
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Published version
Author(s)
Hageman, Tim
Andrade, Carmen
Martínez-Pañeda, Emilio
Type
Journal Article
Abstract
Laboratory and numerical corrosion experiments impose an electric potential on the metal surface, differing from natural corrosion conditions, where corrosion typically occurs in the absence of external current sources. In this work, we present a new computational model that enables predicting corrosion under charge-conservation conditions. The metal potential, an output of the model, is allowed to change, capturing how the corrosion and cathodic reactions must produce/consume electrons at the same rates, as in natural conditions. Finite element simulations are performed over a large range of concentrations and geometric parameters. The results highlight the notable influence of the charge-conservation assumption and pioneeringly quantify corrosion rates under realistic conditions. They further show: (i) the strong coupling between the corrosion rate and the hydrogen and oxygen evolution reactions, (ii) under which circumstances corrosion pits acidify, and (iii) when corrosion is able to become self-sustained lacking oxygen.
Date Issued
2023-09-01
Date Acceptance
2023-05-20
Citation
Electrochimica Acta, 2023, 461, pp.1-13
ISSN
0013-4686
Publisher
Elsevier BV
Start Page
1
End Page
13
Journal / Book Title
Electrochimica Acta
Volume
461
Copyright Statement
© 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
http://dx.doi.org/10.1016/j.electacta.2023.142624
Publication Status
Published
Article Number
142624
Date Publish Online
2023-05-24