Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I)
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Author(s)
Crimmin, MR
Butler, MJ
White, AJP
Type
Journal Article
Abstract
Addition of fluoroarenes, fluoroalkanes or benzofuran to [{(2,6-iPr2C6H3NCMe)2CH}Al] results in facile oxidative addition of either a C–F or C–O bond to the Al(I) centre.
Date Issued
2015-09-14
Date Acceptance
2015-09-14
Citation
Chemical Communications, 2015, 51 (88), pp.15994-15996
ISSN
1364-548X
Publisher
Royal Society of Chemistry
Start Page
15994
End Page
15996
Journal / Book Title
Chemical Communications
Volume
51
Issue
88
Copyright Statement
This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Sponsor
The Royal Society
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Commission of the European Communities
Grant Number
UF090149
EP/L011514/1
EP/K039946/1
655474
Subjects
Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
C-F BOND
ALUMINUM(I) COMPOUND
AL-H
ACTIVATION
RHODIUM
COORDINATION
BORYLATION
COMPLEXES
CLEAVAGE
HYDRODEFLUORINATION
Aluminum
Benzofurans
Fluorobenzenes
Fluorocarbons
Organometallic Compounds
Oxidation-Reduction
Organic Chemistry
03 Chemical Sciences
Publication Status
Published