Near-unity Raman beta-factor of surface-enhanced Raman scattering in a waveguide
File(s)Supplementary_revised_final.pdf (1.74 MB) Main_article_revised_submitted.pdf (1.73 MB)
Supporting information
Accepted version
Author(s)
Type
Journal Article
Abstract
The Raman scattering of light by molecular vibrations is a powerful technique to fingerprint molecules through their internal bonds and symmetries. Since Raman scattering is weak1, methods to enhance, direct and harness it are highly desirable, and this has been achieved using optical cavities2, waveguides3,4,5,6 and surface-enhanced Raman scattering (SERS)7,8,9. Although SERS offers dramatic enhancements2,6,10,11 by localizing light within vanishingly small hot-spots in metallic nanostructures, these tiny interaction volumes are only sensitive to a few molecules, yielding weak signals12. Here we show that SERS from 4-aminothiophenol molecules bonded to a plasmonic gap waveguide is directed into a single mode with >99% efficiency. Although sacrificing a confinement dimension, we find a SERS enhancement of ~103 times across a broad spectral range enabled by the waveguide’s larger sensing volume and non-resonant waveguide mode. Remarkably, this waveguide SERS is bright enough to image Raman transport across the waveguides, highlighting the role of nanofocusing13,14,15 and the Purcell effect16. By analogy to the β-factor from laser physics10,17,18,19,20, the near-unity Raman β-factor we observe exposes the SERS technique to alternative routes for controlling Raman scattering. The ability of waveguide SERS to direct Raman scattering is relevant to Raman sensors based on integrated photonics7,8,9 with applications in gas sensing and biosensing.
Date Issued
2022-10-27
Date Acceptance
2022-09-07
Citation
Nature Nanotechnology, 2022, 17, pp.1251-1257
ISSN
1748-3387
Publisher
Nature Research
Start Page
1251
End Page
1257
Journal / Book Title
Nature Nanotechnology
Volume
17
Copyright Statement
© 2022, The Author(s), under exclusive licence to Springer Nature Limited. This version of the article has been accepted for publication, after peer review (when applicable) and is subject to Springer Nature’s AM terms of use, but is not the Version of Record and does not reflect post-acceptance improvements, or any corrections. The Version of Record is available online at: https://doi.org/10.1038/s41565-022-01232-y
Identifier
https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000874394200002&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Nanoscience & Nanotechnology
Materials Science, Multidisciplinary
Science & Technology - Other Topics
Materials Science
SPECTROSCOPY
NANOANTENNAS
EXCITATION
Publication Status
Published
Date Publish Online
2022-10-27