Localized swelling inhomogeneity detection in lithium ion cells using multi-dimensional laser scanning
File(s)J. Electrochem. Soc.-2019-Zhao-A27-34.pdf (1.24 MB)
Published version
Author(s)
Zhao, Yan
Spingler, Franz B
Patel, Yatish
Offer, Gregory J
Jossen, Andreas
Type
Journal Article
Abstract
The safety, performance and lifetime of lithium-ion cells are critical for the acceptance of electric vehicles (EVs) but the detection of cell quality issues non-destructively is difficult. In this work, we demonstrate the use of a multi-dimensional laser scanning method to detect local inhomogeneities. Commercially available cells with Nickel Cobalt Manganese (NMC) cathode are cycled at various charge and discharge rates, while 2D battery displacement measurements are taken using the laser scanning system. Significant local swelling points are found on the cell during the discharge phase, the magnitude of swelling can be up to 2% of the cell thickness. The results show that the swelling can be aggravated by a combination of slow charge rate and fast discharge rate. Disassembly of the cells shows that the swelling points are matched with the location of ‘adhesive-like’ material found on the electrode surfaces. Scanning Electron Microscope (SEM) images show that the material is potentially blocking the electrodes and separators at these locations. We therefore present laser-scanning displacement as a valuable tool for defect/inhomogeneity detection.
Date Issued
2019-01-04
Date Acceptance
2018-11-30
Citation
Journal of The Electrochemical Society, 2019, 166 (2), pp.A27-A34
ISSN
1945-7111
Publisher
Electrochemical Society
Start Page
A27
End Page
A34
Journal / Book Title
Journal of The Electrochemical Society
Volume
166
Issue
2
Copyright Statement
© 2019 The Author(s). Published by ECS. This is an open access article distributed under the terms of the Creative CommonsAttribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000455039000001&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Technology
Electrochemistry
Materials Science, Coatings & Films
Materials Science
LOW-TEMPERATURE PERFORMANCE
THERMAL-EXPANSION
BATTERY FAILURE
POUCH CELLS
GRAPHITE
INTERCALATION
ELECTRODES
DEPENDENCE
TRANSPORT
DEFECTS
Publication Status
Published
Date Publish Online
2019-01-04