The Goldstone mode and resonances in the fluid interfacial region
File(s)SzL_N.pdf (495.93 KB)
Accepted version
Author(s)
Parry, Andrew
Rascon, Carlos
Type
Journal Article
Abstract
The development of a molecular theory of inhomogeneous fluids and, in particular, of the liquid–gas interface has received enormous interest in recent years; however, long-standing attempts to extend the concept of surface tension in mesoscopic approaches by making it scale dependent, although apparently plausible, have failed to connect with simulation and experimental studies of the interface that probe the detailed properties of density correlations. Here, we show that a fully microscopic theory of correlations in the interfacial region can be developed that overcomes many of the problems associated with simpler mesoscopic ideas. This theory originates from recognizing that the correlation function displays, in addition to a Goldstone mode, an unexpected hierarchy of resonances that constrain severely its structural properties. Indeed, this approach allows us to identify new classes of fully integrable models for which, surprisingly, the tension, density profile and correlation function can all be determined analytically, revealing the microscopic structure of correlations in all generalized van der Waals theories.
Date Issued
2019-03-01
Date Acceptance
2018-10-26
Citation
Nature Physics, 2019, 15, pp.287-292
ISSN
1745-2473
Publisher
Nature Publishing Group
Start Page
287
End Page
292
Journal / Book Title
Nature Physics
Volume
15
Copyright Statement
© 2018 The Author(s), under exclusive licence to Springer Nature Limited.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Grant Number
EP/L020564/1
Subjects
Science & Technology
Physical Sciences
Physics, Multidisciplinary
Physics
LIQUID-VAPOR INTERFACE
SURFACE-TENSION
ENERGY
01 Mathematical Sciences
02 Physical Sciences
Fluids & Plasmas
Publication Status
Published
Date Publish Online
2018-12-10