Metallic MXenes are promising two-dimensional materials for energy storage,
(opto)electronics, and photonics due to their high electrical conductivity and strong light-matter
interaction. Energy dissipation in MXenes is fundamental for photovoltaic and photothermal
applications. Here we apply ultrafast laser spectroscopy across a broad time range (fs-μs) to
study the cooling dynamics of electrons and lattice in emerging Ti2CTx thin films compared to
widely studied Ti3C2Tx thin films. Carrier cooling time in Ti2CTx is persistently ~2.6 ps without
hot-phonon bottleneck. After hot carrier cooling is completed, the transient absorption (TA)
spectra of Ti2CTx MXene can be well described by thermochromic effect. Heat dissipation in
MXene thin films occurs over hundreds of nanoseconds with thermal diffusivity ~ 0.06 mm2
s
−1
for Ti2CTx and ~ 0.02 mm2
s
−1
for Ti3C2Tx, likely due to inefficient inter-flake heat transfer.
Our results unravel the energy dissipation dynamics in Ti2CTx films, showcasing the potential
applications in energy conversion.