Addition of carbon-fluorine bonds to a Mg(I)-Mg(I) bond: an equivalent of Grignard formation in solution
File(s)MgMg_13Sept_markup.pdf (3.69 MB)
Accepted version
Author(s)
Bakewell, C
White, AJ
Crimmin, MR
Type
Journal Article
Abstract
Addition of the carbon-fluorine bond of a series of perfluorinated and polyfluorinated arenes across the Mg-Mg bond of a simple coordination complex proceeds rapidly in solution. The reaction results in the formation of a new carbon-magnesium bond and a new fluorine-magnesium bond and is analogous to Grignard formation in homogeneous solution.
Date Issued
2016-09-16
Date Acceptance
2016-08-06
Citation
Journal of the American Chemical Society, 2016, 138 (39), pp.12763-12766
ISSN
1520-5126
Publisher
American Chemical Society
Start Page
12763
End Page
12766
Journal / Book Title
Journal of the American Chemical Society
Volume
138
Issue
39
Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, © 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/jacs.6b08104.
Sponsor
Commission of the European Communities
The Royal Society
The Leverhulme Trust
Identifier
https://pubs.acs.org/doi/10.1021/jacs.6b08104
Grant Number
677367
UF090149
RPG-2015-248
Subjects
Science & Technology
Physical Sciences
Chemistry, Multidisciplinary
Chemistry
C-F BOND
MAGNESIUM(I) DIMERS
OXIDATIVE ADDITION
BUILDING-BLOCKS
CATALYZED BORYLATION
ACTIVATION
METAL
REAGENTS
HYDRODEFLUORINATION
FLUOROARENES
General Chemistry
03 Chemical Sciences
Publication Status
Published
Date Publish Online
2016-10-05