Generation of plasmonic hot carriers from d-bands in metallic nanoparticles
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Published version
Author(s)
Castellanos, Lara Roman
Kahk, Juhan Matthias
Hess, Ortwin
Lischner, Johannes
Type
Journal Article
Abstract
We present an approach to master the well-known challenge of calculating the contribution of d-bands to plasmon-induced hot carrier rates in metallic nanoparticles. We generalize the widely used spherical well model for the nanoparticle wavefunctions to flat d-bands using the envelope function technique. Using Fermi’s golden rule, we calculate the generation rates of hot carriers after the decay of the plasmon due to transitions either from a d-band state to an sp-band state or from an sp-band state to another sp-band state. We apply this formalism to spherical silver nanoparticles with radii up to 20 nm and also study the dependence of hot carrier rates on the energy of the d-bands. We find that for nanoparticles with a radius less than 2.5 nm, sp-band state to sp-band state transitions dominate hot carrier production, while d-band state to sp-band state transitions give the largest contribution for larger nanoparticles.
Date Issued
2020-03-14
Date Acceptance
2020-03-01
Citation
Journal of Chemical Physics, 2020, 152 (10)
ISSN
0021-9606
Publisher
AIP Publishing
Journal / Book Title
Journal of Chemical Physics
Volume
152
Issue
10
Copyright Statement
© 2020 The Author(s). Published under license by AIP Publishing. All article content, except where otherwise noted, is licensed under a Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/)
Sponsor
Engineering & Physical Science Research Council (E
Engineering & Physical Science Research Council (E
Grant Number
RG72590
EP/L027151/1
Subjects
Science & Technology
Physical Sciences
Chemistry, Physical
Physics, Atomic, Molecular & Chemical
Chemistry
Physics
APPROXIMATION
DECOMPOSITION
ELECTRONS
02 Physical Sciences
03 Chemical Sciences
09 Engineering
Chemical Physics
Publication Status
Published
Article Number
ATRN 104111
Date Publish Online
2020-03-13