Tracking Optical Welding through Groove Modes in Plasmonic Nanocavities
File(s)nl6b02164_si_001.pdf (2.06 MB) manuscript - changes tracked v2.pdf (1.03 MB)
Supporting information
Accepted version
Author(s)
Type
Journal Article
Abstract
We report the light-induced formation of conductive links across nanometer-wide insulating gaps. These are realized by incorporating spacers of molecules or 2D monolayers inside a gold plasmonic nanoparticle-on-mirror (NPoM) geometry. Laser irradiation of individual NPoMs controllably reshapes and tunes the plasmonic system, in some cases forming conductive bridges between particle and substrate, which shorts the nanometer-wide plasmonic gaps geometrically and electronically. Dark-field spectroscopy monitors the bridge formation in situ, revealing strong plasmonic mode mixing dominated by clear anticrossings. Finite difference time domain simulations confirm this spectral evolution, which gives insights into the metal filament formation. A simple analytic cavity model describes the observed plasmonic mode hybridization between tightly confined plasmonic cavity modes and a radiative antenna mode sustained in the NPoM. Our results show how optics can reveal the properties of electrical transport across well-defined metallic nanogaps to study and develop technologies such as resistive memory devices (memristors).
Date Issued
2016-08-16
Date Acceptance
2016-07-20
Citation
Nano Letters, 2016, 16 (9), pp.5605-5611
ISSN
1530-6992
Publisher
American Chemical Society
Start Page
5605
End Page
5611
Journal / Book Title
Nano Letters
Volume
16
Issue
9
Copyright Statement
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, © 2016 American Chemical Society, after peer review and technical editing by the publisher. To access the final edited and published work see http://dx.doi.org/10.1021/acs.nanolett.6b02164.
Sponsor
European Office Of Aerospace Research & Developmen
Engineering & Physical Science Research Council (E
The Royal Society
Engineering and Physical Sciences Research Council
Grant Number
FA9550-14-1-0181
RG72590
IE151097
EP/L027151/1
Subjects
2D materials
Plasmonic nanocavities
light-induced plasmonic welding
nanoparticle on mirror
plasmonic hybridisation
tuneable plasmonics
Nanoscience & Nanotechnology
MD Multidisciplinary
Publication Status
Published