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Construction of an organic cage-based porous ionic liquid using an aminal tying strategy
File(s)
d5me00004a.pdf (758.13 KB)
Published online version
Author(s)
Kai, Aiting
Mroz, Austin
Jelfs, Kim
Cooper, Andrew
Little, Marc
Type
Journal Article
Abstract
An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.
Date Issued
2025-04-02
Date Acceptance
2025-04-01
Citation
Molecular Systems Design & Engineering, 2025
URI
URL
DOI
ISSN
2058-9689
Publisher
Royal Society of Chemistry
Journal / Book Title
Molecular Systems Design & Engineering
Copyright Statement
© The Royal Society of Chemistry and IChemE 2025 Open Access Article. Access Article. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
License URL
Identifier
10.1039/d5me00004a
Publication Status
Published online
Date Publish Online
2025-04-02