Rheological considerations on polymer-based engine lubricants: viscosity index improvers versus thickeners-generalized Newtonian models
Author(s)
Type
Journal Article
Abstract
The development of high-performance lubricants to decrease engine friction and then reduce fuel consumption remains a major challenge for oil manufacturers. Viscosity index improvers (VIIs) are additives used for decades to reduce the dependency of the lubricant's viscosity on temperature to maintain an acceptable lubrication in harsh conditions. Distinction between VIIs and thickeners in realistic engine conditions is of primary interest for oil manufacturers in order to optimize the formulation process. In this context, rheological studies can provide clear insights into the actual effect of such polymeric additives. The behavior of a simplified automotive lubricant is investigated at different temperatures and high pressure and high shear stress and modeling of the properties is proposed. Various polymers of different molecular weights and conformations were mixed in a hydrocracked mineral base oil. The viscosity variations with temperature, pressure, and shear stress, obtained from specific rheometers, were then represented by different models, namely, a Vogel-Fulcher-Tamman expression, a modified Williams-Landel-Ferry correlation, and a Carreau-Yasuda equation. Different rheological responses were observed and allowed the distinction between VIIs and thickeners under different temperature and pressure conditions. The hydrodynamic radii analysis provided an explanation of the rheological responses but also highlighted the limits of the Carreau-Yasuda equation when applied to VIIs. Therefore, the Zhang expression, based on the Maxwell model and applied here to low viscoelastic solutions, is proposed as an appropriate alternative.
Date Issued
2017-08-22
Date Acceptance
2017-06-23
Citation
Tribology Transactions, 2017, 61 (3), pp.437-447
ISSN
1040-2004
Publisher
Taylor & Francis
Start Page
437
End Page
447
Journal / Book Title
Tribology Transactions
Volume
61
Issue
3
Copyright Statement
© 2018 Society of Tribologists and Lubrication Engineers. This is an Accepted Manuscript of an article published by Taylor & Francis in Tribology Transactions on 22 August 2017, available online: https://www.tandfonline.com/doi/full/10.1080/10402004.2017.1346154
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000444573200005&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Engineering, Mechanical
Engineering
Polymeric additives
viscosity index improvers
viscosity thickeners
rheology
viscosity-pressure dependence
viscosity-temperature dependence
generalized Newtonian model
FILM THICKNESS
HIGH-PRESSURE
LIQUIDS
Publication Status
Published
Date Publish Online
2017-06-23