Repository logo
  • Log In
    Log in via Symplectic to deposit your publication(s).
Repository logo
  • Communities & Collections
  • Research Outputs
  • Statistics
  • Log In
    Log in via Symplectic to deposit your publication(s).
  1. Home
  2. Faculty of Natural Sciences
  3. Chemistry
  4. Chemistry
  5. Redefining the dielectric response of nanoconfined liquids: insights from water
 
  • Details
Redefining the dielectric response of nanoconfined liquids: insights from water
File(s)
qp52-s5d5.pdf (632.59 KB)
Published version
Author(s)
Zubeltzu, Jon
Bresme, Fernando
Dawber, Matthew
Fernandez-Serra, Marivi
Artacho, Emilio
Type
Journal Article
Abstract
Recent experiments show that the relative dielectric constant of water confined to a film of nanometric
thickness reaches a strikingly low value of 2.1, barely above the bulk’s 1.8 value for the purely electronic
response. We argue that is not a well-defined measure for dielectric properties at subnanometer scales
due to the ambiguous definition of confinement width. Instead, we propose the 2D polarizability α⊥ as the
appropriate, well-defined response function whose magnitude can be directly obtained from both measurements and computations. Once the appropriate description is used, understanding the interplay between electronic and ionic contributions becomes critical, contrary to what is widely assumed. This highlights the importance of electronic degrees of freedom in interpreting the dielectric response of polar fluids under nanoconfinement conditions, as revealed by molecular dynamics simulations.
Date Issued
2025-10-27
Date Acceptance
2025-10-02
Citation
Physical Review Research, 2025, 7 (4)
URI
https://hdl.handle.net/10044/1/125974
URL
https://journals.aps.org/prresearch/abstract/10.1103/qp52-s5d5
DOI
https://www.dx.doi.org/10.1103/qp52-s5d5
ISSN
2643-1564
Publisher
American Physical Society
Journal / Book Title
Physical Review Research
Volume
7
Issue
4
Copyright Statement
Published by the American Physical Society Published by the American Physical Society under the terms of the Creative Commons Attribution 4.0 International license. Further distribution of this work must maintain attribution to the author(s) and the published article's title, journal citation, and DOI.
License URL
https://creativecommons.org/licenses/by/4.0/
Subjects
Physical Sciences
Physics
Physics, Multidisciplinary
Science & Technology
Publication Status
Published
Article Number
043101
Date Publish Online
2025-10-27
About
Spiral Depositing with Spiral Publishing with Spiral Symplectic
Contact us
Open access team Report an issue
Other Services
Scholarly Communications Library Services
logo

Imperial College London

South Kensington Campus

London SW7 2AZ, UK

tel: +44 (0)20 7589 5111

Accessibility Modern slavery statement Cookie Policy

Built with DSpace-CRIS software - Extension maintained and optimized by 4Science

  • Cookie settings
  • Privacy policy
  • End User Agreement
  • Send Feedback