User-friendly copper-catalysed reduction of azides to amines
File(s)
Accepted version
Author(s)
Pimpasri, Chaleena
White, Andrew
Diez-Gonzalez, Silvia
Type
Journal Article
Abstract
Three homoleptic copper(I) complexes have been prepared and applied to the
reduction of organic azides. Under optimised conditions, complex [Cu(HPDIDMA)2]BF4 3
(
HPDIDMA = 2,6-bis[N-(4-dimethylaminophenyl)carbaldimino]pyridine) could reduce a range
of electron-poor azides in a mixture of DMSO and water without the need of an additional Hsource.
reduction of organic azides. Under optimised conditions, complex [Cu(HPDIDMA)2]BF4 3
(
HPDIDMA = 2,6-bis[N-(4-dimethylaminophenyl)carbaldimino]pyridine) could reduce a range
of electron-poor azides in a mixture of DMSO and water without the need of an additional Hsource.
Date Issued
2020-03
Date Acceptance
2019-10-09
Citation
Asian Journal of Organic Chemistry, 2020, 9 (3), pp.399-403
ISSN
2193-5807
Publisher
Wiley-VCH Verlag
Start Page
399
End Page
403
Journal / Book Title
Asian Journal of Organic Chemistry
Volume
9
Issue
3
Copyright Statement
© 2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: C. Pimpasri, A. J. P. White, S. Díez-González, Asian J. Org. Chem. 2020 , 9 , 399, which has been published in final form at https://doi.org/10.1002/ajoc.201900555
Identifier
https://onlinelibrary.wiley.com/doi/full/10.1002/ajoc.201900555
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
Amines
Azides
Reduction
Copper
Pyridyldi(imine) Ligands
TRANSITION-METAL-COMPLEXES
ARYL HALIDES
SCHIFF-BASE
DERIVATIVES
FUNCTIONALIZATION
REACTIVITY
AMINATION
DIOXYGEN
LIGANDS
0305 Organic Chemistry
Publication Status
Published
Date Publish Online
2019-10-15