Repository logo
  • Log In
    Log in via Symplectic to deposit your publication(s).
Repository logo
  • About
  • Communities & Collections
  • Advanced Search
  • Statistics
  • Log In
    Log in via Symplectic to deposit your publication(s).
  1. Home
  2. Faculty of Engineering
  3. Faculty of Engineering
  4. Membrane-less photoelectrochemical cells: product separation by hydrodynamic control
 
  • Details
Membrane-less photoelectrochemical cells: product separation by hydrodynamic control
File(s)
Membrane-less water splitting.pdf (2.05 MB)
Accepted version
ESI.pdf (288.69 KB)
Supporting information
Author(s)
Holmes-Gentle, Isaac
Hoffmann, Franca
Mesa, Camilo A
Hellgardt, Klaus
Type
Journal Article
Abstract
A key step in order to realise photo-electrochemical (PEC) water splitting to produce hydrogen sustainably, is reactor design. Good engineering will minimise energy losses (both optical and ohmic) due to reactor construction, whilst ensuring the H2 and O2 produced are separated, and this can subsequently relax the requirements on the photo-absorber material and/or electro-catalysts. In this paper we show that separation of the products through hydrodynamic flow alone would negate the need for the conventionally used membrane, which has an associated ohmic drop and cost. This is demonstrated to be possible using a ‘laminar flow between two parallel plates’ reactor design and AR/Pe and AR are found to be the two key dimensionless numbers that predict product cross-over (where AR, Pe are aspect ratio and Péclet number respectively). Supersaturation was used as an indicator of bubble formation, which disrupts the laminar flow required for separation and it is shown that by increasing the reactor pressure, higher current densities can be tolerated before supersaturation occurs. Removal of the dissolved hydrogen and oxygen from electrolyte is discussed. A multi-physics model, which employs an optical transfer matrix method, is used to validate the previous conclusions. Experimental data for hematite and Pt deposited on FTO was used as the anode and cathode respectively. Parasitic optical losses and efficiency improvement with stacking are shown for the example reactor configuration. Additionally, the concept of stacking this reactor design in order to absorb light in multiple passes is introduced. This approach relaxes a classical constraint on photo-absorber materials: large absorption length compared to small diffusion length of charge carriers in the semiconductor.
Date Issued
2017-04-18
Date Acceptance
2017-04-18
Citation
Sustainable Energy and Fuels, 2017, 1 (5), pp.1184-1198
URI
http://hdl.handle.net/10044/1/57262
DOI
https://www.dx.doi.org/10.1039/c7se00176b
ISSN
2398-4902
Publisher
Royal Society of Chemistry
Start Page
1184
End Page
1198
Journal / Book Title
Sustainable Energy and Fuels
Volume
1
Issue
5
Copyright Statement
© The Royal Society of Chemistry 2017
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000422784900026&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Energy & Fuels
Materials Science, Multidisciplinary
Chemistry
Materials Science
MICROFLUIDIC FUEL-CELL
WATER-SPLITTING SYSTEMS
HYDROGEN-PRODUCTION
MATRIX-METHOD
LAMINAR-FLOW
IRON-OXIDE
PERFORMANCE
EFFICIENCY
ELECTRODE
REACTOR
Publication Status
Published
About
Spiral Depositing with Spiral Publishing with Spiral Symplectic
Contact us
Open access team Report an issue
Other Services
Scholarly Communications Library Services
logo

Imperial College London

South Kensington Campus

London SW7 2AZ, UK

tel: +44 (0)20 7589 5111

Accessibility Modern slavery statement Cookie Policy

Built with DSpace-CRIS software - Extension maintained and optimized by 4Science

  • Cookie settings
  • Privacy policy
  • End User Agreement
  • Send Feedback