Capturing first- and second-order behavior in magnetocaloric CoMnSi0.92Ge0.08
File(s)Physical Review B_79_13_2009.pdf (374.27 KB)
Accepted version
Author(s)
Morrison, K
Moore, JD
Sandeman, KG
Caplin, AD
Cohen, LF
Type
Journal Article
Abstract
Here we examine the constituent components that make a magnetocaloric material attractive for application. The field-temperature phase diagram is studied and using calorimetry, the first-order and second-order components of the magnetic field-driven magneto-structural phase transition in CoMnSi0.92Ge0.08 are extracted. It is demonstrated that below 262 K the transition shows a latent heat component associated with first-order behavior when the material changes from antiferromagnetic to ferromagnetic order. Such a transition is known as a metamagnetic transition. We identify 262 K as a tricritical point and above this temperature T-crit the transition shows only continuous, second-order characteristics. Hall-probe imaging that has a five micron pixel resolution is then used to study the striking differences in the spatial evolution of the transition above and below T-crit. We demonstrate that the hysteresis of the transition is linearly related to the magnitude of the latent heat; an observation that has important implications for the use of this and other first-order systems for application as magnetic refrigerants.
Date Issued
2009-04
Citation
PHYS REV B, 2009, 79 (13)
ISSN
1098-0121
Publisher
AMER PHYSICAL SOC
Journal / Book Title
PHYS REV B
Volume
79
Issue
13
Copyright Statement
© 2009 The American Physical Society
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000265942800069&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
ARTN 134408
Publication Status
Published
Article Number
134408