Crystal structure of 1-methylimidazole 3-oxide monohydrate.
File(s)
Published version
Author(s)
Frampton, CS
Murray, JI
Spivey, AC
Type
Journal Article
Abstract
1-Methylimidazole 3-N-oxide (NMI-O) crystallizes as a monohydrate, C4H6N2O·H2O, in the monoclinic space group P21 with Z' = 2 (mol-ecules A and B). The imidazole rings display a planar geometry (r.m.s. deviations = 0.0008 and 0.0002 Å) and are linked in the crystal structure into infinite zigzag strands of ⋯NMI-O(A)⋯OH2⋯NMI-O(B)⋯OH2⋯ units by O-H⋯O hydrogen bonds. These chains propagate along the b-axis direction of the unit cell.
Date Issued
2017-02-14
Date Acceptance
2017-02-08
Citation
Acta Crystallographica Section E: Crystallographic Communications, 2017, 73 (3), pp.372-374
ISSN
2056-9890
Publisher
International Union of Crystallography
Start Page
372
End Page
374
Journal / Book Title
Acta Crystallographica Section E: Crystallographic Communications
Volume
73
Issue
3
Copyright Statement
© 2017 The Author(s) . This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
Identifier
http://www.ncbi.nlm.nih.gov/pubmed/28316812
PII: hb7643
Subjects
1-methyl-2H-imidazole 3-N-oxide
aryl N-oxides
catalysis
crystal structure
hydrate
hydrogen bonding
Publication Status
Published
Coverage Spatial
England