Optimisation of coated nanowire solar cells by simulation
File(s)
Author(s)
Edwards, Thomas
Type
Thesis
Abstract
Radial junction nanowire solar cells are expected to give a higher performance than planar junction solar cells. This is due to the enhanced optical path length for absorption, and the shorter distance for excitons to travel to interfaces where they can dissociate. By means of simulation, we have optimised, with respect to geometrical parameters, solar cells consisting of light absorber coated metal- oxide nanowires. We have primarily studied nanowires with a TiO2 core and CdSe shell, as well as ZnO cores with PbS nanoparticles. Optical scattering and absorption is determined using Finite-Difference Time-Domain (FDTD) simulations. Charge transport is studied using finite-difference drift-diffusion modelling. The generation rate calculated from FDTD is inputted into the charge transport model. The aim is to determine which combination of nanowire parameters (such as coating thickness, height, radius and spacing) lead to the the highest power efficiencies. We found that core and shell thickness has more effect on absorption than nanowire arrangement.
Version
Open Access
Date Issued
2015-11
Date Awarded
2016-07
Copyright Statement
Attribution NoDerivatives 4.0 International Licence (CC BY-ND)
Advisor
Horsfield, Andrew
Haynes, Peter
Harrison, Nicholas
Sponsor
Engineering and Physical Sciences Research Council
Publisher Department
Physics
Publisher Institution
Imperial College London
Qualification Level
Doctoral
Qualification Name
Doctor of Philosophy (PhD)