Solvent–dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2
File(s)
Accepted version
Author(s)
Type
Journal Article
Abstract
The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph]Cl]2 in the solid and solution states are revisited, using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments. The complex was tested for its catalytic activity in the coupling reaction between chlorobenzene and n-hexylamine, where different deactivation behaviour were observed in toluene, 1,4-dioxane and DMF.
Date Issued
2017-05-02
Date Acceptance
2017-05-02
Citation
Dalton Transactions, 2017, 46, pp.7223-7231
ISSN
1477-9226
Publisher
Royal Society of Chemistry
Start Page
7223
End Page
7231
Journal / Book Title
Dalton Transactions
Volume
46
Copyright Statement
© The Royal Society of Chemistry 2017
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Grant Number
EP/G070172/1
Subjects
Palladium
Catalysis
Buchwald-Hartwig cross coupling
Publication Status
Published