Recommendations for reporting equivalent black carbon (eBC) mass concentrations based on long-term pan-European in-situ observations
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Author(s)
Savadkoohi, Marjan
Pandolfi, Marco
Favez, Olivier
Putaud, Jean-Philippe
Eleftheriadis, Konstantinos
Type
Journal Article
Abstract
A reliable determination of equivalent black carbon (eBC) mass concentrations derived from filter absorption photometers (FAPs) measurements depends on the appropriate quantification of the mass absorption cross-section (MAC) for converting the absorption coefficient (babs) to eBC. This study investigates the spatial-temporal variability of the MAC obtained from simultaneous elemental carbon (EC) and babs measurements performed at 22 sites. We compared different methodologies for retrieving eBC integrating different options for calculating MAC including: locally derived, median value calculated from 22 sites, and site-specific rolling MAC. The eBC concentrations that underwent correction using these methods were identified as LeBC (local MAC), MeBC (median MAC), and ReBC (Rolling MAC) respectively. Pronounced differences (up to more than 50 %) were observed between eBC as directly provided by FAPs (NeBC; Nominal instrumental MAC) and ReBC due to the differences observed between the experimental and nominal MAC values. The median MAC was 7.8 ± 3.4 m2 g-1 from 12 aethalometers at 880 nm, and 10.6 ± 4.7 m2 g-1 from 10 MAAPs at 637 nm. The experimental MAC showed significant site and seasonal dependencies, with heterogeneous patterns between summer and winter in different regions. In addition, long-term trend analysis revealed statistically significant (s.s.) decreasing trends in EC. Interestingly, we showed that the corresponding corrected eBC trends are not independent of the way eBC is calculated due to the variability of MAC. NeBC and EC decreasing trends were consistent at sites with no significant trend in experimental MAC. Conversely, where MAC showed s.s. trend, the NeBC and EC trends were not consistent while ReBC concentration followed the same pattern as EC. These results underscore the importance of accounting for MAC variations when deriving eBC measurements from FAPs and emphasize the necessity of incorporating EC observations to constrain the uncertainty associated with eBC.
Date Issued
2024-03-01
Date Acceptance
2024-03-01
Citation
Environment International, 2024, 185, pp.108553-108553
ISSN
0160-4120
Publisher
Elsevier
Start Page
108553
End Page
108553
Journal / Book Title
Environment International
Volume
185
Copyright Statement
/© 2024 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC license (http://creativecommons.org/licenses/by-nc/4.0/).
Identifier
https://www.ncbi.nlm.nih.gov/pubmed/38460240
PII: S0160-4120(24)00139-9
Subjects
Aerosols
Air Pollutants
Carbon
Environmental Monitoring
Particulate Matter
Seasons
Soot
Absorption
eBC
EC
FAPs
MAC
Rolling MAC
Site specific MAC
Publication Status
Published
Coverage Spatial
Netherlands
Article Number
ARTN 108553
Date Publish Online
2024-03-02