Computational study of how inert additives affect the flammability of a polymer
File(s)Nils paper for Imperial repository.pdf (2.34 MB)
Accepted version
Author(s)
Roenner, Nils
Yuan, Han
Kraemer, Roland H
Rein, Guillermo
Type
Journal Article
Abstract
All polymers are flammable to some degree. For safety, polymer flammability is most commonly reduced through flame retardants that are designed to primarily act chemically as opposed to physically. Here, we investigate computationally using the code Gpyro how inert additives such as hollow glass spheres (HGS) and boron nitride platelets (BNP) alter the flammability properties of glass fibre reinforced polybutylene terephthalate (PBT-GF), in a cone heater and UL94 setup. The Gpyro model is first validated against experiments and another code, both from the literature, for pure PBT-GF. According to the predictions, HGS leads to higher surface temperatures but lower temperatures in-depth, whereas adding BNP yields the opposite effect. Modelling numerically the cone heater setup shows that at 50% HGS loading, the time to ignition is reduced to a quarter while the semi-steady state mass loss rate is reduced to a third; at 50% BNP loading, the time to ignition is doubled while the peak mass loss rate is approximately doubled. In the UL94 setup, where the sample is smaller than cone heater, the effects are similar although less pronounced. A sensitivity study of the thermophysical properties shows that time to ignition is primarily controlled by emissivity, density and specific heat capacity, while peak mass loss rate is controlled by thermal conductivity and specific heat capacity. This work shows how heat transfer within a thermoplastic polymer can be utilised to improve its flammability characteristics through inert additives as well as the limitations of this retardancy approach.
Date Issued
2019-06-01
Date Acceptance
2019-04-18
Citation
Fire Safety Journal, 2019, 106, pp.189-196
ISSN
0379-7112
Publisher
Elsevier
Start Page
189
End Page
196
Journal / Book Title
Fire Safety Journal
Volume
106
Copyright Statement
© 2019 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000472128100019&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Technology
Engineering, Civil
Materials Science, Multidisciplinary
Engineering
Materials Science
Modelling
Heat transfer
Ignition
PBT
FLAME-RETARDANT
Publication Status
Published
Coverage Spatial
Nancy, FRANCE
Date Publish Online
2019-04-21