A systematic study on the use of short circuiting for the improvement of proton exchange membrane fuel cell performance
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Accepted version
Author(s)
Gupta, G
Wu, B
Mylius, S
Offer, GJ
Type
Journal Article
Abstract
Proton exchange membrane fuel cells suffer from reversible performance loss during operation caused by the oxidation of the Pt catalyst which in turn reduces the electrochemically active surface area. Many fuel cell manufacturers recommend using short circuiting during the operation of the fuel cell to improve the performance of the cells over time. However, there is lack of understanding on how it improves the performance as well
as on how to optimise the short circuiting strategy for different fuel cell systems. We present a simple procedure to develop an optimised short circuiting strategy by maximising the cumulative average power density gain and minimising the time required to recover the energy loss during short circuiting. We obtained average voltage improvement from 10 to 12% at different current densities for a commercial H-100 system and our short circuiting strategy showed ~2% voltage improvement in comparison to a commercial strategy. We also demonstrated that the minimum short circuiting time is a function of double layer capacitance by the use of electrochemical impedance spectroscopy.
as on how to optimise the short circuiting strategy for different fuel cell systems. We present a simple procedure to develop an optimised short circuiting strategy by maximising the cumulative average power density gain and minimising the time required to recover the energy loss during short circuiting. We obtained average voltage improvement from 10 to 12% at different current densities for a commercial H-100 system and our short circuiting strategy showed ~2% voltage improvement in comparison to a commercial strategy. We also demonstrated that the minimum short circuiting time is a function of double layer capacitance by the use of electrochemical impedance spectroscopy.
Date Issued
2016-11-10
Date Acceptance
2016-10-14
Citation
International Journal of Hydrogen Energy, 2016, 42 (7), pp.4320-4327
ISSN
1879-3487
Publisher
Elsevier
Start Page
4320
End Page
4327
Journal / Book Title
International Journal of Hydrogen Energy
Volume
42
Issue
7
Copyright Statement
© 2016 Elsevier Ltd. All rights reserved.This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (E
Technology Strategy Board
Technology Strategy Board
Identifier
http://www.sciencedirect.com/science/article/pii/S0360319916331007
Grant Number
EP/I038586/1 - Ref: J12967
101980
CHIS_P55265
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Electrochemistry
Energy & Fuels
Chemistry
Proton exchange membrane fuel cells
Short circuit
Pt oxidation
Degradation
OH RADICALS
DEGRADATION
REDUCTION
CATALYSTS
SURFACES
ELECTROCATALYSTS
NANOPARTICLES
OXYGEN
Energy
09 Engineering
03 Chemical Sciences
Publication Status
Published