Thermodynamic stabilization of mixed-halide perovskites against phase segregation
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Published version
OA Location
Author(s)
Type
Journal Article
Abstract
Mixing iodide and bromide in halide perovskite semiconductors is an effective strategy to tune their band gap; therefore, mixed-halide perovskites hold great promise for color-tunable LEDs and tandem solar cells. However, the band gap of mixed-halide perovskites is unstable under (sun-)light, since the halides segregate into domains of different band gaps. Using pressure-dependent ultrafast transient absorption spectroscopy, we find that high external pressure increases the range of stable halide mixing ratios. Chemical compression, by inserting a smaller cation, has the same effect, which means that any iodide:bromide ratio can be stabilized by tuning the crystal volume and compressibility. We interpret these findings as an increased thermodynamic stabilization through alteration of the Gibbs free energy via the largely overlooked PΔV term.
Date Issued
2020-08
Date Acceptance
2020-06-17
Citation
Cell Reports Physical Science, 2020, 1 (8), pp.1-11
ISSN
2666-3864
Publisher
Elsevier BV
Start Page
1
End Page
11
Journal / Book Title
Cell Reports Physical Science
Volume
1
Issue
8
Copyright Statement
© 2020 The Authors.
This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
License URL
Identifier
https://www.sciencedirect.com/science/article/pii/S2666386420301193?via%3Dihub
Publication Status
Published
Article Number
100120
Date Publish Online
2020-07-15