Rheological characterisation of xanthan gum in brine solutions at high temperature
File(s)CarHy_Xanthan_manuscript_R1(20-08-2018).docx (1.59 MB)
Accepted version
Author(s)
Reinoso, D
Martin-Alfonso, MJ
Luckham, PF
Martinez-Boza, FJ
Type
Journal Article
Abstract
Xanthan gum solutions are used in the oil industry for flooding, drilling and completion operations. The stabilization of the structure of xanthan gum solutions in presence of salts increases the value of both the order-disorder transition temperature and the gel strength. This effect is very important in order to design drilling and completion fluids since not only density and viscosity of the fluid can be improved by increasing the concentration of salts but also the range of temperature where the solution shows viscoelastic behaviour can be extended.
This paper presents results from a study on the rheological behaviour of xanthan gum solutions in different saturated brines. Chloride and formate potassium brines not only increase the viscosity of the solution but also extend the shear thinning behaviour to temperatures near 200 °C, maintaining a simple relaxation mechanism over the whole range of temperature where the ordered conformation dominates the rheological behaviour.
This paper presents results from a study on the rheological behaviour of xanthan gum solutions in different saturated brines. Chloride and formate potassium brines not only increase the viscosity of the solution but also extend the shear thinning behaviour to temperatures near 200 °C, maintaining a simple relaxation mechanism over the whole range of temperature where the ordered conformation dominates the rheological behaviour.
Date Issued
2019-01-01
Date Acceptance
2018-09-17
Citation
Carbohydrate Polymers, 2019, 203, pp.103-109
ISSN
0144-8617
Publisher
Elsevier
Start Page
103
End Page
109
Journal / Book Title
Carbohydrate Polymers
Volume
203
Copyright Statement
© 2019 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000447377700012&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Applied
Chemistry, Organic
Polymer Science
Chemistry
Xanthan gum
Formate brine
Rheology
High temperature
FLOW BEHAVIOR
RECOVERY
SYSTEMS
FLUIDS
SALT
GELS
Publication Status
Published
Date Publish Online
2018-09-20