We give relations between main operators of quantum mechanics on one of most general classes of nilpotent Lie groups. Namely, we show relations between momentum and position operators as well as Euler and Coulomb potential operators on homogeneous groups. Homogeneous group analogues of some well-known inequalities such as Hardy's inequality, Heisenberg–Kennard type and Heisenberg–Pauli–Weyl type uncertainty inequalities, as well as Caffarelli–Kohn–Nirenberg inequality are derived, with best constants. The obtained relations yield new results already in the setting of both isotropic and anisotropic Rn, and of the Heisenberg group. The proof demonstrates that the method of establishing equalities in sharper versions of such inequalities works well in both isotropic and anisotropic settings.