Recent developments in polyene cyclizations and their applications in natural product synthesis
File(s)
Author(s)
Barrett, Anthony GM
Ma, Tsz-Kan
Mies, Thomas
Type
Journal Article
Abstract
Cascade polyene cyclization reactions are highly efficient and elegant bioinspired transformations that involve simultaneous multiple bond constructions to rapidly generate complex polycyclic molecules. This review summarizes the most prominent work on a variety of cationic and radical cascade cyclizations and their applications in natural product synthesis published between 2014 and 2018.
Date Issued
2019-01-01
Date Acceptance
2018-10-18
Citation
Synthesis, 2019, 51 (1), pp.67-82
URI
DOI
ISSN
0039-7881
Publisher
Thieme Publishing
Start Page
67
End Page
82
Journal / Book Title
Synthesis
Volume
51
Issue
1
Copyright Statement
© 2019 The Author(s).
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000453240600006&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
polyene cyclization
cascade reaction
carbon-carbon bond formation
natural products
total synthesis
ENANTIOSELECTIVE BIOMIMETIC CYCLIZATION
ASYMMETRIC TOTAL-SYNTHESIS
CASCADE CYCLIZATIONS
TERPENOID POLYALKENES
CATALYZED CYCLOISOMERIZATION
BIOORGANIC CHEMISTRY
ELECTRON-TRANSFER
RADICAL CATIONS
POLYCYCLIZATION
ENTRY
Publication Status
Published
Date Publish Online
2018-11-15