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  4. Oxidation resistant tungsten carbide hardmetals
 
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Oxidation resistant tungsten carbide hardmetals
File(s)
1-s2.0-S0362546X17300871-main.pdf (1.32 MB)
Published version
Author(s)
Humphry-Baker, S
Lee, WE
Peng, K
Type
Journal Article
Abstract
We present a new method for retarding the oxidation rate of hardmetals. By diffusion impregnating a WC-FeCr hardmetal with silicon, we manufacture two-layered silicide coatings consisting of an FeSix outer crust and WSi2 beneath. The structure results from a preferential reaction between silicon and the metallic binder. The FeSix outer layer is crucial to providing oxidation resistance as when exposed to oxygen it passivates, forming a protective SiO2 surface film – while simultaneously preventing exposure of the underlying WSi2, which is known to oxidise in an active manner. Our analysis shows the coating method is applicable to various hardmetals structures.
Date Issued
2017-03-18
Date Acceptance
2017-03-16
Citation
International Journal of Refractory Metals and Hard Materials, 2017, 66, pp.135-143
URI
http://hdl.handle.net/10044/1/45691
URL
https://www.sciencedirect.com/science/article/pii/S0263436816306199?via%3Dihub
DOI
https://www.dx.doi.org/10.1016/j.ijrmhm.2017.03.009
ISSN
0958-0611
Publisher
Elsevier
Start Page
135
End Page
143
Journal / Book Title
International Journal of Refractory Metals and Hard Materials
Volume
66
Copyright Statement
© 2017 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
Sponsor
Tokamak Energy Ltd
Engineering & Physical Science Research Council (E
Identifier
https://www.sciencedirect.com/science/article/pii/S0263436816306199?via%3Dihub
Grant Number
PO TE140409-1
J13614 (EP/K008749/1)
Subjects
Science & Technology
Technology
Materials Science, Multidisciplinary
Metallurgy & Metallurgical Engineering
Materials Science
Metal matrix composites
Weight loss
X-ray diffraction
SEM
Oxidation
TRANSITION-METAL SILICIDES
SILICON DIFFUSION COATINGS
GENERATION IV REACTORS
WC-CO
THERMAL-OXIDATION
CEMENTED CARBIDES
ALLOYS
HARD
BEHAVIOR
TEMPERATURE
0912 Materials Engineering
Materials
Publication Status
Published
Date Publish Online
2017-03-18
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