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  4. Ionic-to-electronic current amplification in hybrid perovskite solar cells: ionically gated transistor-interface circuit model explains hysteresis and impedance of mixed conducting devices
 
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Ionic-to-electronic current amplification in hybrid perovskite solar cells: ionically gated transistor-interface circuit model explains hysteresis and impedance of mixed conducting devices
File(s)
EE-COM-08-2018-002362_R4_Ion-electron-amplification-final.docx (1.48 MB)
Accepted version
Author(s)
Moia, Davide
Gelmetti, Ilario
Calado, Phil
Fisher, William
Stringer, Michael
more
Type
Journal Article
Abstract
Mobile ions in hybrid perovskite semiconductors introduce a new degree of freedom to electronic devices suggesting applications beyond photovoltaics. An intuitive device model describing the interplay between ionic and electronic charge transfer is needed to unlock the full potential of the technology. We describe the perovskite-contact interfaces as transistors which couple ionic charge redistribution to energetic barriers controlling electronic injection and recombination. This reveals an amplification factor between the out of phase electronic current and the ionic current. Our findings suggest a strategy to design thin film electronic components with large, tuneable, capacitor-like and inductor-like characteristics. The resulting simple equivalent circuit model, which we verified with time-dependent drift-diffusion simulations of measured impedance spectra, allows a general description and interpretation of perovskite solar cell behaviour.
Date Issued
2019-04-01
Date Acceptance
2019-03-05
Citation
Energy and Environmental Science, 2019, 12 (4), pp.1296-1308
URI
http://hdl.handle.net/10044/1/74103
DOI
https://www.dx.doi.org/10.1039/c8ee02362j
ISSN
1754-5692
Publisher
Royal Society of Chemistry
Start Page
1296
End Page
1308
Journal / Book Title
Energy and Environmental Science
Volume
12
Issue
4
Copyright Statement
©The Royal Society of Chemistry 2019.
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Identifier
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:000465275800009&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=1ba7043ffcc86c417c072aa74d649202
Grant Number
EP/J002305/1
EP/R511547/1
EP/R020574/1
PO 500215639
Subjects
Science & Technology
Physical Sciences
Technology
Life Sciences & Biomedicine
Chemistry, Multidisciplinary
Energy & Fuels
Engineering, Chemical
Environmental Sciences
Chemistry
Engineering
Environmental Sciences & Ecology
ORGANOMETAL TRIHALIDE PEROVSKITE
THIN-FILM
RECOMBINATION
POLARIZATION
EFFICIENCY
MIGRATION
LENGTHS
ORIGIN
Publication Status
Published
Date Publish Online
2019-03-06
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