Curvature corrections to the nonlocal interfacial model for short-ranged forces
File(s)paper_final.pdf (575.92 KB)
Accepted version
Author(s)
Romero-Enrique, Jose M
Squarcini, A
Parry, AO
Goldbart, PM
Type
Journal Article
Abstract
In this paper we revisit the derivation of a nonlocal interfacial Hamiltonian model for systems with short-ranged intermolecular forces. Starting from a microscopic Landau-Ginzburg-Wilson Hamiltonian with a double-parabola potential, we reformulate the derivation of the interfacial model using a rigorous boundary integral approach. This is done for three scenarios: a single fluid phase in contact with a nonplanar substrate (i.e., wall); a free interface separating coexisting fluid phases (say, liquid and gas); and finally a liquid-gas interface in contact with a nonplanar confining wall, as is applicable to wetting phenomena. For the first two cases our approaches identifies the correct form of the curvature corrections to the free energy and, for the case of a free interface, it allows us to recast these as an interfacial self-interaction as conjectured previously in the literature. When the interface is in contact with a substrate our approach similarly identifies curvature corrections to the nonlocal binding potential, describing the interaction of the interface and wall, for which we propose a generalized and improved diagrammatic formulation.
Date Issued
2018-06-25
Date Acceptance
2018-05-31
Citation
Physical Review E, 2018, 97 (6)
ISSN
1539-3755
Publisher
American Physical Society
Journal / Book Title
Physical Review E
Volume
97
Issue
6
Copyright Statement
© 2018 American Physical Society
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Grant Number
EP/L020564/1
Subjects
Science & Technology
Physical Sciences
Physics, Fluids & Plasmas
Physics, Mathematical
Physics
LIQUID-VAPOR INTERFACE
WEDGE FILLING TRANSITIONS
WAVE-EQUATION
FINITE DOMAIN
MONTE-CARLO
SURFACE
EIGENFREQUENCIES
FIELD
FLUIDS
Publication Status
Published
Article Number
ARTN 062804