A commercially available and user-friendly catalyst for hydroamination reactions under technical conditions
File(s)EJOC_Hydroaminarion_Revision2.pdf (803.94 KB)
Accepted version
Author(s)
Zelenay, Benjamin
Munton, Peter
Tian, Xiaojie
Diez-Gonzalez, Silvia
Type
Journal Article
Abstract
The activity of a simple, commercially available copper salt, [Cu(NCMe)4](BF4) in intramolecular hydroamination reactions of alkynes and allenes is presented. Reactions were successfully carried out in technical acetonitrile in the presence of air. While attempts of alkene hydroamination failed, this catalysts was also found active in intermolecular aza‐Michael reactions.
Date Issued
2019-08-07
Date Acceptance
2019-06-26
Citation
European Journal of Organic Chemistry, 2019, 2019 (29), pp.4725-4730
ISSN
1099-0690
Publisher
Wiley
Start Page
4725
End Page
4730
Journal / Book Title
European Journal of Organic Chemistry
Volume
2019
Issue
29
Copyright Statement
© 2019 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This is the accepted version of the following article: Zelenay, B. , Munton, P. , Tian, X. and Díez-González, S. (2019), A Commercially Available and User‐Friendly Catalyst for Hydroamination Reactions under Technical Conditions. Eur. J. Org. Chem.. Accepted Author Manuscript. doi:10.1002/ejoc.201900701, which has been published in final form at https://dx.doi.org/10.1002/ejoc.201900701
Sponsor
The Royal Society
Grant Number
RG2015 R1
Subjects
Science & Technology
Physical Sciences
Chemistry, Organic
Chemistry
Alkynes
Allenes
Copper
Heterocycles
Hydroamination
ANTI-MARKOVNIKOV HYDROAMINATION
AZA-MICHAEL ADDITION
ONE-POT SYNTHESIS
INTRAMOLECULAR HYDROAMINATION
INTERMOLECULAR HYDROAMINATION
ASYMMETRIC-SYNTHESIS
EFFICIENT SYNTHESIS
TERMINAL ALKYNES
AROMATIC-AMINES
N-H
Organic Chemistry
0305 Organic Chemistry
0304 Medicinal and Biomolecular Chemistry
Publication Status
Published
Date Publish Online
2019-06-26