An oxidation mechanism map for tungsten
File(s)W oxidation map-revised.pdf (876.64 KB)
Accepted version
Author(s)
Nagy, Dóra
Humphry-Baker, Samuel A
Type
Journal Article
Abstract
A tungsten oxidation mechanism map is developed to clarify literature confusion about the dominant oxidation kinetic regime and to enable improved predictions in extreme environments. Thermogravimetry data is systematically extracted from 14 papers in the range 600–1600 °C and treated as three distinct kinetic regimes: parabolic oxidation, linear oxidation, and sublimation. A mechanism map is constructed that shows metal recession thickness contours for each regime in time-temperature space. The map enables consideration of a fusion reactor accident combining loss of coolant and vacuum, in which a tungsten first wall could reach ∼1200 °C for several weeks. Complete oxidation of the first wall and 2 mm of sublimation is predicted. Similar maps must be developed for accident tolerant tungsten alloys if reliable predictions are to be made about their performance.
Date Issued
2022-03
Date Acceptance
2021-10-25
Citation
Scripta Materialia, 2022, 209, pp.1-6
ISSN
1359-6462
Publisher
Elsevier BV
Start Page
1
End Page
6
Journal / Book Title
Scripta Materialia
Volume
209
Copyright Statement
© 2021 Elsevier Ltd. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International Licence http://creativecommons.org/licenses/by-nc-nd/4.0/
Identifier
https://www.sciencedirect.com/science/article/pii/S1359646221006539?via%3Dihub
Subjects
0204 Condensed Matter Physics
0912 Materials Engineering
0913 Mechanical Engineering
Materials
Publication Status
Published
Article Number
114373
Date Publish Online
2021-11-09