Light-intensity and thickness dependent efficiency of planar perovskite solar cells: charge recombination versus extraction
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Author(s)
Type
Journal Article
Abstract
Photoactive layer thickness is a key parameter for optimization of photovoltaic power conversion efficiency (PCE), yet its impact on charge extraction and recombination hasn’t been fully understood in perovskite solar cells (PSCs). Herein we find that in planar PSCs the perovskite thickness yielding maximal PCE is strongly light-intensity dependent. Whilst under 1 sun irradiation the PCE is relatively invariant for perovskite thicknesses between 250 to 750 nm, at lower light intensities (0.1–0.5 sun) the thickest devices yield strongly enhanced PCE, but at higher light intensities (>1 sun) the thinnest devices give optimal PCE. Our results unravel that increased perovskite thickness leads to enhanced light absorption, reduced interfacial recombination at open circuit but greater bimolecular recombination losses at short circuit thus is suitable for devices working under weak illumination, typical of many real-world applications. Reducing perovskite thickness, however, shows the contrast trend and is suitable for PSCs working under concentrated illumination.
Date Issued
2020-08-20
Date Acceptance
2020-08-20
Citation
Journal of Materials Chemistry C, 2020, 8 (36), pp.12648-12655
ISSN
2050-7526
Publisher
Royal Society of Chemistry (RSC)
Start Page
12648
End Page
12655
Journal / Book Title
Journal of Materials Chemistry C
Volume
8
Issue
36
Copyright Statement
© The Royal Society of Chemistry 2020. This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence http://creativecommons.org/licenses/by-nc/3.0/.
License URL
Sponsor
National Research Foundation of Korea (NRF)
Ministry of Science, ICT & Future Planning
Identifier
https://pubs.rsc.org/en/content/articlelanding/2020/TC/D0TC03390A#!divAbstract
Grant Number
NRF-2017K1A1A2013153
NRF-2017K1A1A2013153
Subjects
0303 Macromolecular and Materials Chemistry
0306 Physical Chemistry (incl. Structural)
0912 Materials Engineering
Publication Status
Published
Date Publish Online
2020-08-20