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  4. An easy-to-parameterise physics-informed battery model and its application towards lithium-ion battery cell design, diagnosis, and degradation
 
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An easy-to-parameterise physics-informed battery model and its application towards lithium-ion battery cell design, diagnosis, and degradation
File(s)
WRITTEN_MANUSCRIPT.docx (4.63 MB)
Accepted version
Author(s)
Merla, Y
Wu, B
Yufit, V
Martinez-Botas, RF
Offer, GJ
Type
Journal Article
Abstract
Accurate diagnosis of lithium ion battery state-of-health (SOH) is of significant value for many applications, to improve performance, extend life and increase safety. However, in-situ or in-operando diagnosis of SOH often requires robust models. There are many models available however these often require expensive-to-measure ex-situ parameters and/or contain unmeasurable parameters that were fitted/assumed. In this work, we have developed a new empirically parameterised physics-informed equivalent circuit model. Its modular construction and low-cost parametrisation requirements allow end users to parameterise cells quickly and easily. The model is accurate to 19.6 mV for dynamic loads without any global fitting/optimisation, only that of the individual elements. The consequences of various degradation mechanisms are simulated, and the impact of a degraded cell on pack performance is explored, validated by comparison with experiment. Results show that an aged cell in a parallel pack does not have a noticeable effect on the available capacity of other cells in the pack. The model shows that cells perform better when electrodes are more porous towards the separator and have a uniform particle size distribution, validated by comparison with published data. The model is provided with this publication for readers to use.
Date Issued
2018-04-30
Date Acceptance
2018-02-21
Citation
Journal of Power Sources, 2018, 384 (1), pp.66-79
URI
http://hdl.handle.net/10044/1/58077
URL
https://www.sciencedirect.com/science/article/pii/S0378775318301861
DOI
https://www.dx.doi.org/10.1016/j.jpowsour.2018.02.065
ISSN
0378-7753
Publisher
Elsevier
Start Page
66
End Page
79
Journal / Book Title
Journal of Power Sources
Volume
384
Issue
1
Copyright Statement
© 2018 Elsevier B.V. All rights reserved. This manuscript is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License http://creativecommons.org/licenses/by-nc-nd/4.0/
Sponsor
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (E
Engineering & Physical Science Research Council (EPSRC)
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://www.sciencedirect.com/science/article/pii/S0378775318301861
Grant Number
EP/K002252/1
J15119 - PO:500174140
EP/I00422X/1
EP/I00422X/1
Subjects
Science & Technology
Physical Sciences
Technology
Chemistry, Physical
Electrochemistry
Energy & Fuels
Materials Science, Multidisciplinary
Chemistry
Materials Science
Lithium ion battery
Modelling
Empirical
Parameterisation
Physics model
Degradation
SOLID-ELECTROLYTE INTERPHASE
DIFFERENTIAL THERMAL VOLTAMMETRY
EQUIVALENT-CIRCUIT MODELS
HYBRID-ELECTRIC VEHICLES
DOUBLE-LAYER CAPACITANCE
HIGH-POWER
AUTOMOTIVE APPLICATIONS
ELECTROCHEMICAL MODEL
C-6/LIFEPO4 BATTERIES
CATHODE MATERIALS
Energy
03 Chemical Sciences
09 Engineering
Publication Status
Published
Date Publish Online
2018-03-23
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