Influence of dispersant and ZDDP on soot wear
File(s)Kontou2018_Article_InfluenceOfDispersantAndZDDPOn.pdf (7.83 MB)
Published version
Author(s)
Kontou, A
Southby, M
Morgan, N
Spikes, HA
Type
Journal Article
Abstract
Diesel engines and gasoline direct injection (GDI) engines both produce soot due to incomplete combustion of the fuel and some enters the lubricant where it accumulates between drain intervals, promoting wear of rubbing engine components. Currently the most favoured mechanism for this wear is that the anti-wear additives present in engine oils, primarily zinc dialkyldithiophosphates (ZDDPs), react very rapidly with rubbing surfaces to form relatively soft reaction products. These are easily abraded by soot, resulting in a corrosive-abrasive wear mechanism. This study has explored the impact of engine oil dispersant additives on this type of wear using combinations of dispersant, ZDDP and carbon black, a soot surrogate. It has been found that both the concentration and type of dispersant are critical in influencing wear. With most dispersants studied, wear becomes very high over an intermediate dispersant concentration range of ca 0.1–0.4 wt% N, with both lower and higher dispersant levels showing much less wear. However a few dispersants appear able to suppress high wear by ZDDP and carbon black over the whole concentration range. A series of experiments have been carried out to determine the origin of this behaviour and it is believed that high levels of dispersant, and, for a few dispersants, all concentration levels, protect the iron sulphide tribofilm initially formed by ZDDP from abrasion by carbon black.
Date Issued
2018-12-01
Date Acceptance
2018-10-24
Citation
Tribology Letters, 2018, 66 (4), pp.1-15
ISSN
1023-8883
Publisher
Springer
Start Page
1
End Page
15
Journal / Book Title
Tribology Letters
Volume
66
Issue
4
Copyright Statement
© 2018 The Author(s). Open Access. This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Sponsor
Shell Research Limited
Engineering & Physical Science Research Council (EPSRC)
Identifier
https://link.springer.com/article/10.1007%2Fs11249-018-1115-x
Grant Number
See further information
EP/P030211/1
Subjects
Science & Technology
Technology
Engineering, Chemical
Engineering, Mechanical
Engineering
Soot wear
ZDDP
Corrosive-abrasive wear
Dispersant
Succinimide
Carbon black
DIESEL-ENGINE
TRIBOLOGICAL BEHAVIOR
LUBRICANT ADDITIVES
OIL
PARTICLES
CONTAMINATION
CARBON
Mechanical Engineering & Transports
0912 Materials Engineering
0913 Mechanical Engineering
Publication Status
Published
Article Number
157
Date Publish Online
2018-11-09