What is the order of a reaction?
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Published version
Author(s)
Bures, Jordi
Type
Journal Article
Abstract
The order of a reaction in some species seems an obvious, trivial concept that all chemists master. However, in complex situations such as catalytic systems, the order of a reaction is not always that simple: it can be partial, negative and function of other parameters. In order to analyze rate laws and experimental orders of complex reaction networks, it is necessary to have a proper mathematical description of what the order of a reaction is. In general, chemists working in catalysis are unaware that such a mathematical description exists and therefore they are restricted to analyzing only extreme limit cases of rate laws. This manuscript offers a description and a simple demonstration of this concept, known as elasticity coefficient or normalized sensitivity. It also presents several examples of applications on classic and usual catalytic scenarios.
Date Issued
2017-06-01
Date Acceptance
2017-05-01
Citation
Topics in Catalysis, 2017, 60 (8), pp.631-633
ISSN
1022-5528
Publisher
Springer Verlag
Start Page
631
End Page
633
Journal / Book Title
Topics in Catalysis
Volume
60
Issue
8
Copyright Statement
© 2017 The Author(s). This article is distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.
Subjects
Science & Technology
Physical Sciences
Chemistry, Applied
Chemistry, Physical
Chemistry
Order
Elasticity coefficient
Rate laws
Kinetics
Publication Status
Published
Date Publish Online
2017-05-09