Robocasting of MgO-doped alumina using alginic acid slurries
File(s)
Author(s)
Glymond, Daniel
Vandeperre, LJM
Type
Journal Article
Abstract
The benefits of MgO doping of alumina for maintaining a homogeneous grain structure have long been established. Therefore in this work a bespoke ink for Robocasting of alumina is developed based on the gelation of alginic acid using magnesium ions, thereby ensuring homogeneous MgO doping of the alumina green body. The shear thinning behavior of alginic acid based solutions was paired with the rheological properties of a partially coagulated colloidal suspension to allow high solid loading inks (up to 50 vol%) with good extrusion behavior. Shear thinning coefficients of n ~ 0.2 were recorded, with yield stresses of 250 Pa and stiffness values in the range 100-1000 kPa. The printed alumina bars reached densities of >98% and unpolished strengths reached up to 326 ± 16 MPa after sintering at 0.4 mol/L magnesium chloride and 45 vol% alumina.
Date Issued
2018-08-01
Date Acceptance
2018-02-09
Citation
Journal of the American Ceramic Society, 2018, 101 (8), pp.3309-3316
ISSN
0002-7820
Publisher
Wiley
Start Page
3309
End Page
3316
Journal / Book Title
Journal of the American Ceramic Society
Volume
101
Issue
8
Copyright Statement
© 2018 The American Ceramic Society. This is the pre-peer reviewed version of the following article, which has been published in final form at http://onlinelibrary.wiley.com/doi/10.1111/jace.15509/abstract
Sponsor
SAFRAN POWER UNITS SAS
Grant Number
6000002410-1
Subjects
Science & Technology
Technology
Materials Science, Ceramics
Materials Science
alumina
printing
processing
rheology
rheometry
strength
PHOSPHATE SCAFFOLDS
HYDROGEL
BEHAVIOR
INKS
0912 Materials Engineering
0913 Mechanical Engineering
Materials
Publication Status
Published
Date Publish Online
2018-02-28